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" Organic synthesis using samarium diiodide : "
David J. Procter, Robert A. Flowers and Troels Skrydstrup.
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BL
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| Record Number
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1037208
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b791578
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| Main Entry
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Procter, David J.
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| Title & Author
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Organic synthesis using samarium diiodide : : a practical guide /\ David J. Procter, Robert A. Flowers and Troels Skrydstrup.
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| Publication Statement
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Cambridge :: Royal Society of Chemistry,, 2010.
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| Page. NO
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1 online resource (xvi, 205 pages) :: illustrations
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| ISBN
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1628708751
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: 184973075X
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: 9781628708752
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: 9781849730754
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1847551106
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9781847551108
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| Bibliographies/Indexes
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Includes bibliographical references and index.
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| Contents
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9781847551108; i_iv; v_vi; vii; viii; ix_xiii; xiv_xvi; 001_004; 005_019; 020_035; 036_068; 069_144; 145_156; 157_197; 198_204.
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| Abstract
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Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectiv.
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| Subject
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Organic compounds-- Synthesis.
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Samarium-- Reactivity.
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Samarium.
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Organic compounds-- Synthesis.
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Samarium.
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SCIENCE-- Chemistry-- Inorganic.
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| Dewey Classification
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546.415
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| LC Classification
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QD262.P76 2010eb
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| Added Entry
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Flowers, Robert A.
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Skrydstrup, Troels.
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