Document Type
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BL
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Record Number
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1046184
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Doc. No
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b800554
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Title & Author
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Carbon-centered free radicals and radical cations : : structure, reactivity, and dynamics /\ edited by Malcolm D. Forbes.
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Publication Statement
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Hoboken, NJ :: Wiely,, ©2010.
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Series Statement
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Wiley Series of Reactive Intermediates in Chemistry and Biology ;; v.2
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Page. NO
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1 online resource (xxii, 370 pages)
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ISBN
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0470390093
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: 0470584106
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: 0470584114
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: 1282490885
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: 6612490888
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: 9780470390092
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: 9780470584101
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: 9780470584118
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: 9781282490888
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: 9786612490880
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9780470390092
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Bibliographies/Indexes
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Includes bibliographical references and index.
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Contents
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CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 4. Selectivity in Radical Cation Cycloadditions; 5. The Stability of Carbon-Centered Radicals; 6. Interplay of Stereoelectronic Vibrational and Environmental Effects in Tuning Physicochemical Properties of Carbon-Centered Radicals.
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Abstract
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The chemistry and biochemistry of reactive intermediates is central to modern mechanistic and quantitative understanding of organic chemistry and biochemistry. The only comprehensive review to cover carbon-centered radical intermediates and their role(s) in chemistry and biochemistry, Carbon-Centered Radicals provides detailed explanations of the role of these intermediates in organic reactions and detailed discussions of their versatility with respect to functional groups to help graduate students and professional researchers better understand and expand their synthetic utility.
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Subject
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Carbon, Activated.
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Subject
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Cations.
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Subject
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Free radicals (Chemistry)
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Subject
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Reactivity (Chemistry)
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Subject
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Carbon, Activated.
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Subject
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Cations.
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Subject
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Free radicals (Chemistry)
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Subject
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Reactivity (Chemistry)
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Subject
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SCIENCE-- Chemistry-- Organic.
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Dewey Classification
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547/.1224
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LC Classification
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QD471.C337 2010eb
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Added Entry
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Forbes, Malcolm D. E.,1960-
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