New palladium and platinum complexes based on ligands bearing nitronylnitroxide radicals. Magnetic p...

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" New palladium and platinum complexes based on ligands bearing nitronylnitroxide radicals. Magnetic properties and catalytic activity in oxidation of alcohols "
Ahsan Mushir Shemsi

Document Type	:	Latin Dissertation
Language of Document	:	English
Record Number	:	54653
Doc. No	:	TL24607
Call number	:	‭3334186‬
Main Entry	:	Ahsan Mushir Shemsi
Title & Author	:	New palladium and platinum complexes based on ligands bearing nitronylnitroxide radicals. Magnetic properties and catalytic activity in oxidation of alcohols\ Ahsan Mushir Shemsi
College	:	King Fahd University of Petroleum and Minerals (Saudi Arabia)
Date	:	2008
Degree	:	Ph.D.
student score	:	2008
Page No	:	268
Abstract	:	In the last two decades the field of molecular magnetic materials has become a rapidly growing interdisciplinary area in pure and applied sciences. These materials find their application in developing magnetic devices, molecular electronics, nonlinear optics, sensing devices, nanosized materials and catalysts. Coordination chemistry provides a powerful tool to design these materials in the form of discrete molecular systems, 1D chains, 2D layers or 3D networks. In the present study new palladium(II) and platinum(II) transition metal complexes based on mixed ligands 2,2'-bipyridine and 1,10-phenanthroline and their dimethyl substituted derivatives with different pyridylnitronylnitroxide were successfully synthesized. Characterization of these complexes using elemental analysis, UV-visible, FT-IR and ESR spectroscopy was carried out. The magnetic susceptibility of a series of compounds was measured down to 4 Kelvin. Cyclic voltametry studies were performed on these complexes to investigate the behavior of the electroactive centers and determine the different redox couples. Single crystal X-ray diffraction analyses were conducted on a series of complexes to determine their solid state molecular structure and the nature of their packing modes in order to rationalize their physical properties. Different pyridylnitronylnitroxide radicals synthesized in the present study were used for the first time to evaluate their catalytic activity in the oxidation of alcohols.
Subject	:	Applied sciences; Alcohols; Nitronylnitroxide radicals; Oxidation; Palladium; Platinum; Chemical engineering; 0542:Chemical engineering
Added Entry	:	King Fahd University of Petroleum and Minerals (Saudi Arabia)