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" S Sulfur-Nitrogen Compounds Part 8 "
by Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Reimund Jotter, Birgit Ledüc ; edited by Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Reimund Jotter, Alfons Kubny.
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BL
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578656
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b407875
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| Main Entry
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Baumann, Norbert.
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| Title & Author
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S Sulfur-Nitrogen Compounds Part 8 : Compounds with Sulfur of Oxidation Number IV /\ by Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Reimund Jotter, Birgit Ledüc ; edited by Norbert Baumann, Hans-Jürgen Fachmann, Brigitte Heibel, Reimund Jotter, Alfons Kubny.
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| Edition Statement
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8th Edition.
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| Publication Statement
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Berlin, Heidelberg :: Springer Berlin Heidelberg :: Imprint: Springer,, 1991.
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| Series Statement
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Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition ;; S / S-N / 8
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9783662063637
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: 9783662063651
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| Abstract
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PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.
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Chemistry.
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Fachmann, Hans-Jürgen.
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Heibel, Brigitte.
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Jotter, Reimund.
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Ledüc, Birgit.
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Baumann, Norbert.
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Fachmann, Hans-Jürgen.
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Heibel, Brigitte.
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Jotter, Reimund.
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Kubny, Alfons.
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SpringerLink (Online service)
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