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" Organo main group chemistry / "
Kin-ya Akiba
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BL
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| Record Number
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657226
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dltt
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| Main Entry
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Akiba, Kinʼya,1936-
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| Title & Author
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Organo main group chemistry /\ Kin-ya Akiba
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| Page. NO
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xi, 275 pages :: illustrations ;; 24 cm
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| ISBN
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9780470450338
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: 0470450339
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| Bibliographies/Indexes
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Includes bibliographical references and index
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| Contents
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Main group elements and heteroatoms: scope and characteristics -- Notes 1: electronegativity -- Notes 2: importance of formal logic-I: oxidation number and formal charge -- Notes 3: importance of formal logic-II: octet rule, eighteen-electron rule, hypervalence -- Main group element effect -- Notes 4: ([lower case sigma, lower case sigma*) and (lower case pi, lower case pi*): HMO (Hueckel Molecular Orbital) and electrocyclic reaction -- Lithium, magnesium, and copper compounds -- Boron and aluminum compounds -- Silicon, tin, and lead compounds -- Notes 5: stable carbene and its complex -- Phosphorus,, antimony, and bismuth compounds -- Notes 6: dreams of Staudinger and Wittig -- Notes 7: stereochemistry in nucleophilic substitution of MX₄-type compounds: inversion or retention -- Sulfur, selenium, and tellurium compounds -- Notes 8: inversion mechanism of NH₃ and NF₃: vertex inversion or edge inversion -- Organohalogen compounds: fluorine and iodine compounds -- Atrane and transannular interaction: formation of hypervalent bond -- Unsaturated compounds of main group elements of third period and heavier -- Ligand coupling reaction -- Notes 9: hexavalent organotellurium compounds -- Hypervalent carbon compounds: can hexavalent carbon exist? -- Notes 10: main group element porphyrins
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| Abstract
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"This book will capture the essential scope of organic chemistry of all main group elements and covers all main group elements dealing with syntheses and reactions of their organic compounds. While organic compounds of second row elements centered at carbon are the major components of animals and plants, those of the third row and below are also important and have unique roles which this book discusses. The first eight chapters are arranged according to the periodic table, starting with the role of lithium and magnesium cations (positively charged ions) in synthesis to fluorine and iodine compounds. The last four chapters deal with modern topics that were selected on the basis of unique characteristics of main group elements compared to the carbon (i.e. main group element effect is placed as the central idea to arrange and unify.)"--
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Organic compounds
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Organic compounds-- Synthesis
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Carbon compounds
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Chemistry, Organic
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| LC Classification
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QD251.3.A35 2011
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