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" Organometallic Compounds : "
by G.E. Coates, M.L.H. Green, K. Wade.
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BL
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726530
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b546262
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| Main Entry
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by G.E. Coates, M.L.H. Green, K. Wade.
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Organometallic Compounds : : Volume Two. The Transition Elements\ by G.E. Coates, M.L.H. Green, K. Wade.
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| Publication Statement
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Dordrecht: Springer Netherlands, 1968
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| ISBN
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9401168938
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: 9401168954
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: 9789401168939
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: 9789401168953
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| Contents
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To Volume Two --;Classification --;The 18-electron rule --;1. Two-Electron Ligands --;A. Classification --;B. The preparation of olefin-transition metal complexes --;C.A molecular orbital description of the bonding in organo-metallic complexes --;D.A description of the bonding of 2-electron ligands to transition metals --;E. General comments of 2-electron ligands --;F. Particular complexes of metals with 2-electron ligands --;2. Three-Electron Ligands --;A. Preparation of?-enyl complexes --;B. The structure of?-enyl complexes --;C. The?-allyl metal bond --;D. Dynamic equilibria in allyl complexes --;E. The chemistry of particular?-enyl complexes --;3. Four-Electron Ligands --;A. Some differences between unconjugated and conjugated olefin ligands --;B. The bonding of 4-electron ligands to transition metals --;C. Particular studies --;4. Five-Electron Ligands --;A. Cyclopentadienyl metal complexes --;B.?-Cyclopentadienyl transition metal complexes --;C. Cyclopentadienide transition metal complexes --;D. The bonding in mono-?-cyclopentadienyl transition metal complexes --;E.?-Cyclopentadienyl carbonyl complexes --;F.?-Cyclopentadienyl nitrosyl complexes --;G. Brief notes on binuclear?-cyclopentadienyl complexes containing bridging ligands --;H.?-Cyclopentadienyl hydride complexes --;I.?-Cyclopentadienyl halides and oxides --;J. Other 5-electron ligands --;K. The organic chemistry of?-cyclopentadienyl transition metal complexes --;L. Some particular reactions --;5. Six-Electron Ligands --;A. Arene transition metal complexes --;(a) Preparation --;B. Olefin 6-electron ligands --;C. Transition metal complexes containing?-bonded heterocyclic ligands --;6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes --;A. 7-Electron ligands --;B. Mixed sandwich complexes --;C. Metal complexes formed from azulenes --;D. Cyclo-octatetraene complexes --;7. One-Electron Ligands --;I.1. Hydrocarbon alkyl and aryl complexes --;I.2 Transition metal-acyl complexes --;I.3.?-Cyclopentadienyl complexes --;II. Transition metal fluorocarbon complexes --;III. Transition metal acetytides and alkynyls --;8. Organometallic Complexes Formed From Acetylenes --;A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands --;B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands --;C. Monoacetylene trinuclear complexes --;D. Monoacetylene tetranuclear complexes --;E. Bis-acetylene mononuclear complexes --;F. Bis-acetylene trinuclear complexes --;G. Tris-acetylene mononuclear complexes --;H. Tris-acetylene binuclear complexes --;I. Miscellaneous --;9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions --;A. Some chemistry of transition metal hydride complexes --;B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions --;C. Homogeneous hydrogenation of olefins and acetylenes --;D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes --;E. Hydroformylation and related carhonylation reactions --;F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts --;G. Miscellaneous --;Author --;Subject --;Crystal Structures>
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| Abstract
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Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p.
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Physical Sciences Mathematics.
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Science (General)
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Science.
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| LC Classification
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QD411.B944 1968
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| Added Entry
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G E Coates
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K Wade
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M L H Green
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