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" Advances in Corrosion Science and Technology : "
edited by Mars G. Fontana, Roger W. Staehle.
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BL
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| Record Number
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727971
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b547708
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| Main Entry
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edited by Mars G. Fontana, Roger W. Staehle.
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| Title & Author
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Advances in Corrosion Science and Technology : : Volume 4\ edited by Mars G. Fontana, Roger W. Staehle.
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| Publication Statement
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Boston, MA: Springer US, 1974
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(volumes)
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| ISBN
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1461590590
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: 1461590612
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: 9781461590590
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: 9781461590613
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| Contents
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1 The Mechanical Properties and Breakdown of Surface Films at Elevated Temperatures.- Stresses Developed During Isothermal Oxidation.- Volume Ratio of the Metal and the Oxide Produced.- Influence of Epitaxial Relationships between Metal and Surface Oxide.- Effect of Composition Changes in the Metal and Oxide during Exposure.- Influence of Vacancy Generation in the Substrate Metal.- Influence of Specimen Geometry on Stresses Developed in Surface Oxides.- Stresses Developed During Thermal Cycling Conditions.- Effect of Superimposed Stresses on the Mechanical Stability of Oxide Scales.- Behavior of Bulk Oxides under Stress.- Behavior of Surface Oxides under Stress.- Methods of Measuring Mechanical Properties of Oxides.- Measurement of Internal Stresses in Surface Oxides.- Measurement of Elastic and Plastic Properties of Oxides.- Measurement of Interfacial Adhesive Properties.- Mechanisms of Stress Relief.- Elastic Failure of the Scale.- Stress Relief by Plastic Deformation of the Scale.- Deformation of the Substrate Metal.- Detachment at the Metal-Scale Interface.- Influence of Corrosive Contaminants on Oxide Stability.- Methods of Improving Mechanical Properties of Surface Oxides.- General Conclusions.- References.- 2 Anodic Dissolution of Metals-Anomalous Valence.- Transitory or Uncommon Ion Mechanism.- Related Phenomena.- Anodic Disintegration.- Film Control Mechanisms.- Difference Effect.- Anodic Dissolution of Metals.- Aluminum, Gallium, Indium, and Thallium.- Beryllium and Magnesium.- Zinc and Cadmium.- Discussion.- References.- 3 Corrosion of Metals in Organic Solvents.- Classification of Organic Solvents According to Their Properties And Corrosivities.- Solvation in Organic Solvents-Protic and Aprotic Solvents.- One-Component and Multicomponent Systems.- One-Phase and Multiphase Systems.- Thermodynamics and Stoichiometry.- Reaction Types and Stoichiometry.- General Thermodynamic Relationships and Calculations.- Acidity in Amphiprotic Media.- pH Values in Organic Solvents.- Electrochemical Acidity Functions in Organic Solvents.- Electrode Potentials in Organic Solvents.- Corrosion Potentials in Organic Solvents.- Kinetics and Mechanisms.- Solvent Properties Important for Reaction Kinetics.- Discussion of Partial Reactions and Their Parameters.- Influence of the Metal Phase.- Influence of the Medium Phase.- Electrode Potentials and Currents.- Influence of Temperature.- Electrochemical and "Chemical" Corrosion Mechanisms.- Mechanistic Findings on Specific Corrosion Phenomena- Cracking.- Borderline Mechanisms to High-Temperature Corrosion.- Corrosion Failures and Their Prevention.- Case Histories.- Tabular Summary of Corrosion Failures and Their Prevention.- Phenomenology of Attack-Deterioration of the Environment.- Principles of Corrosion Prevention in Organic Solvents.- Conclusions.- References.- 4 Chromium Depletion and Void Formation in Fe-Ni-Cr Alloys During Molten Salt Corrosion and Related Processes.- Chemical Reactions.- Molten Fluoride Salts.- Molten Chloride Salts.- Liquid Metals.- Oxidation.- Reducing, Oxidizing, and Carburizing Environments, Including Hot Corrosion.- Heat Treatment.- Vaporization.- Sensitization.- Sigma Formation.- Summary.- References.
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| Subject
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Science (General)
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| LC Classification
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TA418.74E358 1974
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| Added Entry
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Mars G Fontana
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R W Staehle
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