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" State-to-state dynamical research in the F+H2 reaction system / monograph. "
Zefeng Ren.
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BL
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| Record Number
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748147
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b568103
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| Main Entry
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Zefeng Ren.
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| Title & Author
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State-to-state dynamical research in the F+H2 reaction system / monograph.\ Zefeng Ren.
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| Publication Statement
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Berlin : Springer, 2014
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| Series Statement
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Springer theses.
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| Page. NO
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xii, 77 pages : illustrations (some color) ; 24 cm.
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| ISBN
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3642397557
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: 3642397565
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: 9783642397554
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: 9783642397561
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| Contents
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Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus --; Dynamical Resonances in F+H2 Reactions --; The Non-Adiabatic Effects in F(2P)+D2?DF+D.
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| Abstract
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This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.
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| Subject
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Chemical reactions.
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Hydrogen.
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Rydberg states.
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| LC Classification
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QD501.Z444 2014
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| Added Entry
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Zefeng Ren
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