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" The Metal-Hydrogen System : "
by Yuh Fukai.
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BL
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759271
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b579242
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| Main Entry
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by Yuh Fukai.
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| Title & Author
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The Metal-Hydrogen System : : Basic Bulk Properties\ by Yuh Fukai.
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| Publication Statement
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Berlin, Heidelberg : Springer Berlin Heidelberg, 1993
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| Series Statement
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Springer series in materials science, 21.
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(x, 355 pages)
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| ISBN
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3662028018
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: 9783662028018
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| Contents
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1 Phase Diagrams and Statistical Thermodynamics of Binary M-H Systems --; 1.1 Introduction to Phase Diagrams --; 1.2 Formation of Solid Solutions --; 1.3 Spinodal Decomposition --; 1.4 Formation of Hydrides --; 1.5 Other General Issues Regarding the Relative Phase Stability --; 2 Hydrogen in Alloys --; 2.1 Effects of Alloying on the Solubility --; 2.2 Effects of Alloying on the Terminal Solubility --; 2.3 Hydrogen --; Solute Interaction --; Trapping and Blocking --; 2.4 Hydrogen in Amorphous Alloys --; 3 Metal --; Hydrogen System Under Extended p, T Conditions --; 3.1 Hydrogen --; 3.2 Volume of Hydrogen in Metals --; 3.3 Solubility Enhancement Under High Hydrogen Pressures --; 3.4 Phase Diagrams Under Extended p, T Conditions --; 4 Atomistic States of Hydrogen in Metals --; 4.1 Site Location by the Channeling Method --; 4.2 X-Ray Diffraction and Scattering --; 4.3 Neutron Diffraction --; 4.4 Inelastic Neutron Scattering --; 4.5 Some Specific Problems of Site Occupancy --; 4.6 Theory of the Atomistic State of Hydrogen in Metals --; 5 Diffusion --; 5.1 Introduction --; 5.2 Experimental Methods --; 5.3 Experimental Results on Diffusion Coefficients --; 5.4 Experimental Results on the Diffusion Mechanism --; 5.5 Diffusion in Inhomogeneous Systems --; 5.6 Theoretical Considerations on the Diffusion Mechanism --; 5.7 Critical Analysis of the Experimental Data in Terms of the Quantum Theory of Diffusion --; Addendum 5A: Two-Site Tunneling of Hydrogen in?-ScH x --; Addendum 5B: Stress-Enhanced Diffusion? --; 6 Electronic Structure --; 6.1 Hydrogen-Induced Changes in the Electronic Structure of Metal Hydrides --; 6.2 Energies of Hydride Formation --; 6.3 Hydrogen --; Metal Interaction Potential --; 6.4 Electronic Structure of Metallic Hydrogen --; References --; List of Symbols --; List of Abbreviations.
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| Abstract
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This coherent description of the basic bulk properties of the metal-hydrogensystem emphasizes the underlying physics, leading to an understanding of how the various properties come about. Among the topics treated are: - phase relations over wide ranges of pressure, temperature, and composition - the site preference, quantum-mechanical states, and motion (diffusion, quantum-mechanical tunneling) of interstitial hydrogen atoms - a brief description of the relevant electronic structure . Comprehensive compilations of data and literature references round off this volume, making it an invaluable asset to all researchers and students interested in fundamental aspects and technological applications of the metal-hydrogen system.
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Physical organic chemistry.
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Physics.
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Yuh Fukai
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