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" Rubber Chemistry "
by J.A. Brydson.
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BL
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| Record Number
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774091
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b594085
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| Main Entry
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by J.A. Brydson.
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Rubber Chemistry\ by J.A. Brydson.
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| Publication Statement
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Dordrecht : Springer Netherlands, 1979
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(458 pages)
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| ISBN
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9400992211
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: 9400992238
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: 9789400992214
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: 9789400992238
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| Contents
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1 The Historical Development of Rubber Chemistry.- 1.1. Introduction.- 1.2. Early Years.- 1.3. Synthetic Rubber.- 1.4. Hot and Cold War: Hot and Cold Rubber.- 1.5. Stereo and Speciality Rubbers.- 1.6. Reactivity of Rubbers.- 1.7. Future Trends.- 2 The Chemical Nature of the Natural Rubber Molecule.- 2.1. Introduction.- 2.2. The Chemical Formula of Natural Rubber.- 2.3. Molecular Weight and the Molecular Weight Distribution.- 2.4. Minor Groupings and Microgel.- 2.5. End-groups.- 2.6. The Protein Effect.- 3 The Molecular Nature of Rubber Elasticity.- 3.1. Introduction.- 3.2. Molecular Dimensions.- 3.3. Elasticity of a Single Chain.- 3.4. Elasticity of a Network.- 3.5. Non-Gaussian Networks.- 3.6. Alternative Relationships.- 3.7. Thermodynamic Aspects.- 3.8. Conclusions.- 4 Structure-Property Relationships in Rubbers.- 4.1. Basic Considerations.- 4.2. Non-rubbery Properties.- 4.3. Structure and Processing Properties.- 4.4. Strength of Rubbers.- 5 Diene Homopolymer Rubbers.- 5.1. Introduction.- 5.2. Preparation of Monomers.- 5.3. Isomerism in Diene Rubbers.- 5.4. Characterization of Microstructure.- 5.5. Polymerization of Dienes.- 5.6. Structure and Properties of Diene Rubbers.- 6 Diene-Based Copolymers.- 6.1. Introduction.- 6.2. Copolymer Structure-General Considerations.- 6.3. Styrene-Butadiene Rubber.- 6.4. Nitrile Rubbers.- 6.5. Vinyl Pyridine Rubbers.- 6.6. Butadiene-Methyl Isopropenyl Ketone Rubbers.- 6.7. Alternating Olefin-Diolefin Copolymers.- 7 Reactivity of Diene Rubbers-I.- 7.1. General Considerations.- 7.2. Reactivity of Alkenes.- 7.3. Hydrogenation.- 7.4. Hydrohalogenation.- 7.5. Halogenation.- 7.6. Cis-Trans-Isomerization.- 7.7. Cyclized Rubber.- 7.8. Maleic Derivatives.- 7.9. Epoxidized, Hydroxy-esterified and Hydroxy-halogenated Diene Polymers.- 7.10. 'Ene' and 1, 3-Dipolar Reactions.- 7.11. Conclusions.- 8 Reactivity of Diene Rubbers-II: Cross-Linking Processes.- 8.1. Introduction.- 8.2. Accelerated Sulphur Vulcanization.- 8.3. Vulcanization by Sulphur-containing Compounds.- 8.4. Vulcanization without Sulphur or Sulphur Compounds.- 9 Reactivity of Diene Rubbers-III: Oxidation And Related Processes.- 9.1. Introduction.- 9.2. Oxidation of Saturated and Unsaturated Hydrocarbons.- 9.3. Oxidation of Sulphides and Olefin-Sulphide Systems.- 9.4. Oxidation of Diene Rubber Network Structures.- 9.5. Protection against Oxidation.- 9.6. Mastication, Oxidation and Mechanochemistry.- 9.7. Reaction of Ozone with Diene Rubbers.- 10 Polychloroprene.- 10.1. Introduction.- 10.2. Monomer Preparation and Properties.- 10.3. Polymerization.- 10.4. Polymer Structure.- 10.5. Vulcanization.- 10.6. Oxidation and Ageing.- 10.7. Technological Comparison of Polychloroprenes.- 11 Polyisobutene and Butyl Rubber.- 11.1. Introduction.- 11.2. Polymerization Chemistry and Manufacture.- 11.3. Structure of Polyisobutene and Butyl Rubber.- 11.4. Halogenation of Butyl Rubber.- 11.5. Identification and Characterization.- 11.6. Cross-linking of Butyl.- 11.7. Miscellaneous Butyl-type Rubbers.- 12 Rubbers Based on Ethylene.- 12.1. Introduction.- 12.2. Ethylene-Propylene Rubbers.- 12.3. Rubbery Copolymers of Ethylene with Polar Monomers.- 12.4. Chlorinated and Chlorosulphonated Polymers.- 13 Fluorine-Containing Rubbers.- 13.1. Introduction.- 13.2. Early Developments.- 13.3. Copolymers Containing Vinylidene Fluoride.- 13.4. Copolymers Containing Perfluoro (Methyl Vinyl Ether).- 13.5. Nitroso-fluoroelastomers.- 13.6. Phosphonitrile Fluoroelastomers.- 13.7. Perfluoroalkylenetriazine Elastomers.- 13.8. Poly(Thiocarbonyl Fluoride) and Related Elastomers.- 13.9. Miscellaneous Fluoroelastomers.- 14 Acrylic Rubbers.- 14.1. Introduction.- 14.2. General Polymerization Chemistry of Acrylic Rubbers.- 14.3. The Development of Oil-resistant Rubbers with Low Brittle Point.- 14.4. Reactive Cure Sites.- 14.5. Curing Systems.- 14.6. Ageing of Acrylic Rubbers.- 14.7. Polyvinyl Ether Elastomers.- 15 Rubbers Produced by Condensation and Ring Opening Polymerization Mechanisms.- 15.1. Introduction.- 15.2. Polyesters and Polyester-amides.- 15.3. Polyamides.- 15.4. Polyethers and Polythioethers.- 15.5. Polysulphides.- 15.6. The Silicones.- 15.7. Polyalkenamers.- 15.8. Polynorbornene.- 16 Polyurethane Rubbers.- 16.1. Introduction.- 16.2. Intermediates, Structure and Properties.- 16.3. Cross-linking and Physical Properties.- 16.4. Cast Polyurethane Rubbers.- 16.5. Millable Gums.- 16.6. Cellular Polyurethanes.- 16.7. Thermoplastic Polyurethanes.- 16.8. Toxicity Hazards in Polyurethane Technology.- 17 Thermoplastic Rubbers.- 17.1 Introduction.- 17.2. Block Copolymers.- 17.3. Survey of Industrial Block Copolymer Thermoplastic Rubbers.
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| Subject
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Polymers.
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| Subject
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Surfaces (Physics)
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| LC Classification
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TS1892.B953 1979
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| Added Entry
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J A Brydson
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