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BL
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| Record Number
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843739
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| Main Entry
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Butler, James N.
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| Title & Author
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Carbon Dioxide Equilibria and Their Applications
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| Publication Statement
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Milton :: Routledge,, 2018.
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| Page. NO
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1 online resource (273 pages)
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| ISBN
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1315138778
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: 1351462598
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: 9781315138770
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: 9781351462594
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1138430137
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9780873716246
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9781138430136
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| Notes
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Formulation as an Equilibrium Problem
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| Contents
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Cover; Title Page; Copyright Page; Preface; Table of Contents; CHAPTER ONE: Review of Solubility and pH Calculations; Converting Chemical Models to Mathematical Problems; Logarithmic and Exponential Functions; A Note on Calculators; Strong Acids and Bases; Weak Acids; Titration with Strong Base; Weak bases; Polyprotic Acids; Buffers; Solubility Product; Problems; CHAPTER TWO: The Basic Equations; Henry's Law; Hydration; Ionization; pH Dependence, Constant Partial Pressure; The Charge Balance in the Presence of Base; Alkalinity; Acidity; Solution without Gas Phase
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Charge Balance and Proton ConditionRelation between Alkalinity, pH, and CT; Acidity with Constant CT; A Note on Concentration Units; Ionic-Strength Effects; The Davies Equation; Effect of Ionic Strength on KH; Effect on Ionic Strength on First Acidity Constant Ka1; Effect of Ionic Strength on Second Acidity Constant Ka2; Effect of Ionic Strength on Ion Product of Water; Effect of Ionic Strength on Solubility Product of CaCO3; Problems; CHAPTER THREE: The Alkalinity Titration Curve; The Titration Curve Equation; Titration Error; Effect of Ionic Strength
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Ion Pairing in SeawaterTotal Alkalinity and Carbonate Alkalinity in Seawater; Field Observations of Seawater; The Lysocline; Effect of Increased Atmospheric CO2 on the Oceans; Fresh Waters and Estuarine Waters; Brines; Hydrothermal Solutions; Problems; CHAPTER SIX: Engineering Applications: Water Conditioning; Estimation of Ionic Strength; pH Adjustment by Addition of Acid or Base; Addition or Removal of CO2; Addition of Lime; Addition of Limestone; The Langelier Index of CaCO3 Saturation; Corrosion Inhibition; The Lime-Soda Water Softening Process; Stoichiometric Calculations
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Solution without Gas PhaseAddition of Strong Acid or Base in the Presence of CaCO3 without Gas Phase; Limited Amount of CaCO3 at Constant Cr; Buffer Index at Constant P with CaCO3 Present; Buffer Index at Constant CT with CaCO3 Present; Buffer Index with Constant D; Problems; CHAPTER FIVE: Applications to Geochemistry and Oceanography; Rainwater; Acid Rain; River Water; Unsaturated CaCO3 as a Model for River and Groundwater; Saturated CO2, CaCO3, and H2O as a Model for River and Groundwater; Other Components of River Water; Seawater; Seawater as a Constant Ionic Strength Medium
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Total Alkalinity and Carbonate AlkalinityLinearized (Gran) Titration Curves; Linearizing the Acid Portion of the Alkalinity Titration; Linearizing the HCO3̄ Region; Other Linearized Portions of the Alkalinity Titration Curve; The CO3̄ Equivalence Point; Alkalinity Titration in Seawater; The Buffer Index; Buffer Index at Constant CT; Buffer Index at Constant P; Problems; CHAPTER FOUR: Solubility Equilibria: Calcium Carbonate; Calcium Carbonate, Carbon Dioxide, and Water; Dolomite; Addition of Strong Base or Strong Acid at Constant P; Limited Amount of CaCO3 in the Presence of Strong Acid
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| Subject
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Carbon dioxide.
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Carbonates.
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Chemical equilibrium.
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Carbon dioxide.
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Carbonates.
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Chemical equilibrium.
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| Dewey Classification
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546/.6812
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| LC Classification
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QD181.C1
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