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BL
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| Record Number
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859745
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| Title & Author
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Polymer/POSS nanocomposites and hybrid materials : : preparation, properties, applications /\ Susheel Kalia, Krzysztof Pielichowski, editors.
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| Publication Statement
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Cham :: Springer,, [2018]
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| Series Statement
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Springer Series on Polymer and Composite Materials.
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| Page. NO
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1 online resource
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| ISBN
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3030023265
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: 3030023273
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: 9783030023263
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: 9783030023270
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9783030023263
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| Contents
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Intro; Preface; Contents; About the Editors; Synthesis Routes of POSS; 1 Introduction; 2 Synthetic Methodologies; 2.1 Solgel Synthetic Procedures; 2.2 Corner Capping of Partially Condensed POSS; 2.3 Cleavage of Completely Condensed POSS; 2.4 Hydrosilylation for the Preparations of T8R8, T8R7R2, and T_8 R_7 -- n R^_n POSS; 2.5 Microwave Irradiation Procedures; 2.6 High Yield and/or Facile Functionalization Methods for Novel Functional POSS-An Overview; 3 Characterization Procedures; 3.1 NMR Characterization of POSS; 3.2 Vibrational Spectroscopy; 3.3 X-Ray Diffraction
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2 Polyolefin/POSS Nanocomposites2.1 Polyethylene/POSS; 2.2 Polypropylene/POSS; 2.3 Ethylene-Propylene Copolymer/POSS; 2.4 Composites of Vinyl Polymers with POSS; 3 Reactive Mixing of Polyolefins and POSS; 3.1 Reactive Mixing Processes and Phase Interactions; 3.2 Morphology and Structure of PP-g-POSS Composites; 3.3 Crystallization Behaviour and Thermal Degradation; 3.4 Mechanical and Rheological Properties; 4 Applications; 5 Concluding Remarks; References; Polyurethane/POSS Hybrid Materials; 1 Introduction; 2 Chemical Modifications
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2 POSS Crystal Packing and Hierarchical Structures in the Solid State2.1 Monofunctional POSS; 2.2 Heterofunctional POSS; 3 Mesomorphic Behaviour of POSS Crystals; 4 Advanced Hybrid Materials Based on POSS Self-assembling Phenomena; 4.1 Surfactants; 4.2 Hybrid POM-POSS Clusters and Related Structures; 4.3 3D Nanonetworks; 4.4 Templating with POSS; 4.5 POSS-Containing Hybrid Materials for Optoelectronics; 4.6 Supramolecular Bioactive POSS Nanoassemblies; 4.7 Self-assembly of POSS at the Interface; 5 Conclusions and Perspectives; References; Polyolefins with POSS; 1 Introduction
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2.1 POSS Molecules as Pendant Groups in the Polyurethane Chain2.2 POSS Incorporated in the Main Chain; 2.3 POSS in a Polyurethane Network Node; 3 Physical Blending; 4 Application of PU-POSS Hybrid Materials; 5 Conclusions; References; POSS-Containing Polyamide-Based Nanocomposites; 1 Introduction; 1.1 POSS; 1.2 Polyamides; 2 Polyamides-POSS Nanocomposites; 2.1 Incorporation of POSS in Polyamides; 2.2 POSS-Polymer Interaction; 3 PA-POSS Structure and Morphology; 3.1 Morphology of POSS-Containing PA-Polymer Blends; 4 PA-POSS Functional Properties; 4.1 Mechanical Properties
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3.4 MALDI-TOF Characterization3.5 XPS Characterization; 3.6 SEC-GPC Characterization; 3.7 TGA Characterization; 4 Conclusions; References; Design and Synthesis of Hybrid Materials with POSS; 1 Preface; 2 Polyhedral Oligomeric Silsesquioxane (POSS); 3 Polymer/POSS Hybrid Nanomaterial; 4 Interaction in Polymer/POSS; 5 Design and Fabrication Strategies for Polymer/POSS Hybrid; 6 Structure-Property Relationship in Polymer/POSS Hybrid System; 7 Challenges and Future Scenarios; 8 Summary; References; Self-assembly of POSS-Containing Materials; 1 Introduction
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| Abstract
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This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS' role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.
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| Subject
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Nanostructured materials.
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| Subject
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Nanostructured materials.
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| Dewey Classification
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620.1/15
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| LC Classification
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TA418.9.N35
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| Added Entry
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Kalia, Susheel
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Pielichowski, Krzysztof
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