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" Titration calorimetry : "
Lee D. Hansen, Mark K. Transtrum, Colette F. Quinn.
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BL
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| Record Number
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865633
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| Main Entry
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Hansen, Lee D.
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| Title & Author
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Titration calorimetry : : from concept to application /\ Lee D. Hansen, Mark K. Transtrum, Colette F. Quinn.
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| Publication Statement
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Cham, Switzerland :: Springer,, [2018]
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, ©2018
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| Series Statement
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SpringerBriefs in molecular science
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1 online resource
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| ISBN
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3319782509
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: 9783319782508
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3319782495
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9783319782492
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Includes bibliographical references.
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| Contents
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Intro; Preface; Acknowledgement; Contents; Chapter 1: Introduction to Calorimetry; Chapter 2: Introduction to Titration Calorimetry; Chapter 3: Determination of Equilibrium Constants by Titration Calorimetry; 3.1 Introduction to Chemical Equilibrium; 3.2 Analysis of Calorimetric Titration Data for Concentrations of Reactants; 3.3 Analysis of Calorimetric Titration Data for Reaction Enthalpy Change, DeltarH; 3.4 Analysis of Calorimetric Titration Data for Simultaneous Determination of Equilibrium Constants (K), Enthalpy Changes (Del ...
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3.5 Conditions for Simultaneous Determination of K, DeltarH, and n3.6 General Procedure for Simultaneous Determination of K, DeltarH, and n; 3.7 Temperature Dependencies of K and DeltarH; 3.8 Choosing a Reaction Model; 3.9 Some General Rules for Estimating K and DeltarH for Reactions; 3.10 Uncertainties in Results of Simultaneous Determination of K, DeltarH, and n; Chapter 4: Determination of Reaction Kinetics by Calorimetry; 4.1 Introduction to Chemical Kinetics; 4.2 Reactions with Rate Determined by a Catalyst; 4.3 Reactions with Rate Determined by Activities of Reactants.
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4.4 Temperature Dependence of the Rate ConstantChapter 5: Statistics of Curve Fitting; 5.1 Introduction; 5.2 The Least Squares Estimator; 5.3 Finding the Best Fit; 5.4 The Meaning of Statistical Uncertainty; 5.5 Confidence Intervals; 5.6 Parameter Correlations; 5.7 Asymptotic Inference, Jackknife, and Bootstrap; 5.8 Global Fits to Multiple Data Sets; Chapter 6: Related Topics in Calorimetry; 6.1 Analytical Applications of Titration Calorimetry; 6.2 Temperature Scanning Calorimetry; 6.3 Pressure Scanning Calorimetry; 6.4 Biocalorimetry; Chapter 7: Self-test Questions; Chapter 8: Self-test Key.
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| Abstract
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This Brief describes the calibration of titration calorimeters (ITCs) and calculation of stoichiometry, equilibrium constants, enthalpy changes, and rate constants for reactions in solution. A framework/methodology for model development for analysis of ITC data is presented together with methods for assessing the uncertainties in determined parameters and test data sets. This book appeals to beginners, as well as to researchers and professionals in the field.
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Calorimetry.
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Volumetric analysis.
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Calorimetry.
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Medical research.
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Mensuration systems of measurement.
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Physical chemistry.
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SCIENCE-- Mechanics-- Thermodynamics.
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Volumetric analysis.
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| Dewey Classification
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536.6
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| LC Classification
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QC291
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| Added Entry
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Quinn, Colette F.
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Transtrum, Mark K.
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