Document Type
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BL
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Record Number
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874422
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Main Entry
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Larson, Richard A.
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Title & Author
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Reaction Mechanisms in Environmental Organic Chemistry
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Publication Statement
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Boca Raton :: Routledge,, 2018.
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Page. NO
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1 online resource (448 pages)
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ISBN
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0203741242
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: 1351419714
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: 9780203741245
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: 9781351419710
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1351419722
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9781351419727
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Contents
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Cover; Title Page; Copyright Page; Dedication; Preface; Table of Contents; 1: ORGANIC CHEMICALS IN THE ENVIRONMENT; Environmental Fates of Organic Chemicals; The Carbon Cycle; Translocation of Organic Chemicals; Volatilization; Transport Within the Aqueous Phase; Partition into Solid Phases; Transformation of Organic Compounds; Reaction Mechanisms; Kinetics; Linear Free Energy Relationships; Overview of the Environment; The Troposphere and the Stratosphere; The Thermal Structure of the Atmosphere; Solar Energy Distribution; Chemical Constituents and Their Reactions; Natural Waters
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Clays and Clay MineralsNatural Organic Matter; Dissolved Organic Matter; Soil and Sediment-Associated Organic Matter; References; 3: REDUCTION; Introduction; Reductive Transformation Pathways; Nitroaromatic Reduction; Polynitro Aromatics; Regioselectivity; Aromatic Azo Reduction; N-Nitrosoamine Reduction; Sulfoxide Reduction; Quinone Reduction; Reductive Dealkylation; Reductive Dehalogenation; Halogenated Aliphatics; Halogenated Aromatics; Reduction Kinetics; One-Electron Transfer Scheme; Structure Reactivity Relationships for Reductive Transformations; Electron-Mediated Reductions
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Combustion and Incineration
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Natural Organic MatterMineral Systems; Microbial-Mediated Reductions; Effects of Sorption on Reduction Kinetics; References; 4: ENVIRONMENTAL OXIDATIONS; Molecular Oxygen; Autooxidation; Polymers; Petroleum; Superoxide; Singlet Oxygen; Ozone and Related Compounds: Photochemical Smog; Hydrogen Peroxide and Its Decay Products; H2O2; Hydroxyl Radical; Formation; Reactions with Organic Compounds; Daughter Radicals: Bromide, Carbonate, etc; Peroxy Radicals; Alkoxy and Phenoxy Radicals; Surface Reactions; Clays; Silicon Oxides; Aluminum Oxides; Iron Oxides; Manganese Oxides; Thermal Oxidations
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Nucleophilic Acyl SubstitutionAddition-Elimination Mechanism; Functional Group Transformation by Nucleophilic Acyl Substitution Reactions; Carboxylic Acid Derivatives; Carbonic Acid Derivatives; Other Nucleophilic Substitution Reactions; Reactions with Naturally Occurring Nucleophiles; Nucleophilic Reactivity; Reactions of Sulfur-Based Nucleophiles with Halogenated Aliphatics; Neighboring Group Participation (Intramolecular Nucleophilic Displacement); Catalysis of Hydrolytic Reactions in Natural Aquatic Ecosystems; General Acid and Base Catalysis; Metal Ion Catalysis; Surface-Bound Metals
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Water as Solvent and ReactantMarine Waters and Estuaries; Lakes and Rivers; The Air-Water Interface: The Surface Microlayer; Groundwater; Organic Matter in Aquatic Environments; Solid Phases; Soil Structure; Aquatic Sediments; Soil Organic Matter; References; 2: HYDROLYSIS; Introduction; Hydrolysis Kinetics; Specific Acid and Base Catalysis; pH Dependence; Hydrolysis Reaction Mechanisms; Nucleophilic Substitution; SnI Mechanism; Sn2 Mechanism; Functional Group Transformation by Nucleophilic Substitution Reactions; Halogenated Aliphatics; Epoxides; Organophosphorus Esters
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Subject
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Environmental chemistry.
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Subject
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Organic compounds-- Environmental aspects.
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Subject
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Organic reaction mechanisms.
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Subject
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Chemische Reaktion
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Subject
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Chimie de l'environnement.
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Subject
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Composés organiques-- Aspect de l'environnement.
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Subject
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Environmental chemistry.
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Subject
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Ökologische Chemie
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Subject
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Organic compounds-- Environmental aspects.
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Subject
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Organic reaction mechanisms.
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Subject
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Organische Verbindungen
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Subject
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Réactions chimiques.
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Subject
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Reaktionsmechanismus
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Subject
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TECHNOLOGY ENGINEERING-- Environmental-- General.
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Subject
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Umweltanalytik
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Subject
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Umweltverschmutzung
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Subject
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Ethnology-- Periodicals.
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Subject
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Chemische reacties.
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Subject
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Milieuchemie.
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Subject
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Organische verbindingen.
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Subject
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Reactiemechanismen (chemie)
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Dewey Classification
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628.5
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LC Classification
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TD196.O73
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Added Entry
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Weber, Eric J.
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