Document Type
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BL
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Record Number
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889067
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Main Entry
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Xia, Wei
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Title & Author
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Fabrication of metal--organic framework derived nanomaterials and their electrochemical applications /\ Wei Xia.
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Publication Statement
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Singapore, Singapore :: Springer,, [2018]
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Series Statement
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Springer theses,
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Page. NO
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1 online resource :: illustrations (some color)
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ISBN
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9789811068119
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: 9811068119
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9789811068102
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9811068100
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Notes
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Originally presented as the author's thesis (doctoral)--Beijing da xue.
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Bibliographies/Indexes
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Includes bibliographical references.
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Contents
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Intro; Supervisor's Foreword; Abstract; Parts of this thesis have been published as the following journal articles:; Contents; 1 Introduction; 1.1 Metal-Organic Framework Nanomaterials; 1.1.1 Brief Introduction of Metal-Organic Frameworks; 1.1.2 The Characters of Metal-Organic Frameworks; 1.1.3 The Synthesis of Metal-Organic Frameworks; 1.1.4 Applications of Metal-Organic Frameworks; 1.2 Metal-Organic Framework Derived Nanomaterials; 1.2.1 Metal-Organic Framework Derived Porous Carbons; 1.2.2 Metal-Organic Framework Derived Metal Oxides.
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1.2.3 Metal-Organic Framework Derived Metal Oxide/Carbon Composites1.2.4 Other Metal-Organic Framework Derived Inorganic Compounds; 1.3 The Application of MOF-Derived Materials in Electrochemical Energy Storage and Conversion; 1.3.1 MOF-Derived Materials for Supercapacitor; 1.3.2 MOF-Derived Materials for Lithium-Ion Batteries; 1.3.3 MOF-Derived Materials for Fuel Cells; 1.3.4 Applications in Other Electrochemical Processes; 1.4 The Significance of This Study and Research Content; References; 2 Synthesis and Characterization of MOF-Derived Nanomaterials; 2.1 Instruments and Chemicals.
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2.1.1 Instruments2.1.2 Chemicals Used in Synthesis of N-Doped Nanoparticles; 2.1.3 Chemicals Used in Synthesis of Core-Shell Metal Oxide Nanoparticles; 2.1.4 Chemicals Used in Synthesis of Hollow Metal Oxide Nanoparticles; 2.1.5 Chemicals Used in Synthesis of 3D Porous Carbon; 2.2 Synthesis of N-Doped Carbon Nanoparticles; 2.2.1 Synthesis of Co-MOF with Different Sizes; 2.2.2 Synthesis of Multi-component ZnCo-MOF; 2.2.3 Synthesis of N-Doped Carbon Nanomaterials; 2.3 Synthesis of Core-Shell Metal Oxide Nanoparticles; 2.3.1 Synthesis of Ordered Porous Carbon Matrix; 2.3.2 Zif-9@CM.
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2.3.3 Synthesis of Core-Shell Metal Oxide Nanoparticles2.4 Synthesis of Hollow Metal Oxide Nanoparticles; 2.4.1 Synthesis of Nitrogen-Doped Graphene Aerogel; 2.4.2 Nitrogen-Doped Graphene Aerogel Supported Co-MOF; 2.4.3 Synthesis of Hollow Metal Oxide Nanoparticles; 2.5 Synthesis of 3D Porous Carbon; 2.5.1 Synthesis of Metal-Organic Aerogel/Xerogel; 2.5.2 Synthesis of 3D Porous Carbon from MOA; 2.5.3 Synthesis of Porous Carbon from MOX; 2.6 Characterization of Materials; 2.6.1 X-Ray Diffraction (XRD); 2.6.2 Thermogravimetric Analysis (TGA); 2.6.3 Energy Dispersive Spectroscopy (EDS).
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2.6.4 X-Ray Photoelectron Spectroscopy (XPS)2.6.5 Inductively Coupled Plasma (ICP); 2.6.6 Raman Spectroscopy; 2.6.7 Nitrogen Sorption Measurement; 2.6.8 Scanning Electron Microscope (SEM); 2.6.9 Transmission Electron Microscope (TEM); 2.7 Electrochemical Measurements; 2.7.1 ORR Measurements; 2.7.2 Battery Test; References; 3 Formation of N-Doped Carbon Nanomaterials for ORR Catalysis and Li Storage; 3.1 Introduction; 3.2 Synthesis of N-Doped Carbon Nanoparticles; 3.2.1 Formation of Co-MOFs of Different Particle Sizes; 3.2.2 Formation of Multi-component ZnCo-MOF.
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Abstract
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This thesis systematically introduces readers to a new metal-organic framework approach to fabricating nanostructured materials for electrochemical applications. Based on the metal-organic framework (MOF) approach, it also demonstrates the latest ideas on how to create optimal MOF and MOF-derived nanomaterials for electrochemical reactions under controlled conditions. The thesis offers a valuable resource for researchers who want to understand electrochemical reactions at nanoscale and optimize materials from rational design to achieve enhanced electrochemical performance. It also serves as a useful reference guide to fundamental research on advanced electrochemical energy storage materials and the synthesis of nanostructured materials.
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Subject
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Nanostructured materials.
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Subject
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Organometallic polymers.
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Subject
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Supramolecular organometallic chemistry.
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Subject
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Nanostructured materials.
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Subject
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Organometallic polymers.
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Subject
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SCIENCE-- Chemistry-- Organic.
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Subject
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Supramolecular organometallic chemistry.
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Dewey Classification
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547.0504426
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LC Classification
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QD882
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