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" Enzymatic polymerization towards green polymer chemistry / "
Shiro Kobayashi, Hiroshi Uyama, Jun-ichi Kadokawa, editors.
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BL
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| Record Number
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891241
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| Title & Author
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Enzymatic polymerization towards green polymer chemistry /\ Shiro Kobayashi, Hiroshi Uyama, Jun-ichi Kadokawa, editors.
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| Publication Statement
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Singapore :: Springer,, 2019.
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| Series Statement
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Green chemistry and sustainable technology,
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1 online resource (x, 389 pages) :: illustrations (some color)
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| ISBN
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9789811338137
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: 9789811338144
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: 9811338132
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: 9811338140
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9789811338120
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9811338124
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| Contents
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Intro; Preface; Contents; Contributors; Chapter 1: Introduction; 1.1 Introduction; 1.1.1 Historical Background of Enzymatic Polymerization; 1.1.2 Characteristics of Enzymatic Polymerization; 1.1.3 Green Polymer Chemistry; 1.2 Chapter Relations; References; Chapter 2: Synthesis of Polysaccharides I: Hydrolase as Catalyst; 2.1 Introduction; 2.2 General Introduction of Glycosidases; 2.3 Cellulase; 2.3.1 Enzymatic Polymerization of Cellobiosyl Monomers Catalyzed by Cellulase; 2.3.2 Enzymatic Polymerization of Other Saccharide Monomers Catalyzed by Cellulases
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2.4 Xylanase, 4-Glucanohydrolase, and Amylase2.5 Glycosidase Catalysis for Ring-Opening Polyadditions; 2.6 Chitinase; 2.6.1 Enzymatic Polymerization of Chitobiose Oxazoline Monomer Catalyzed by Chitinase: Artificial Chitin; 2.6.2 Chitinase-Catalyzed Synthesis of Unnatural Oligo- and Polysaccharides; 2.7 Hyaluronidase; 2.7.1 Hyaluronidase-Catalyzed Synthesis of Hyaluronan and Chondroitin; 2.7.2 Unnatural Hybrid-Type Glycosaminoglycan Synthesis; 2.8 Keratanase; 2.9 Perspective; References; Chapter 3: Synthesis of Polysaccharides II: Phosphorylase as Catalyst
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5.4 ConclusionReferences; Chapter 6: Synthesis of Polyesters II: Hydrolase as Catalyst for Ring-Opening Polymerization; 6.1 Introduction; 6.2 Enzymatic ROP of Cyclic Esters; 6.3 Enzymatic Copolymerization of Cyclic Esters; 6.4 Enantioselective and Chemoselective ROP; 6.5 Enzymatic Terminal Functionalization via ROP; 6.6 Solvent for Enzymatic ROP; 6.7 Chemoenzymatic Synthesis of Functional Polymers; 6.8 Other Cyclic Monomers; 6.9 Conclusion; References; Chapter 7: Synthesis of Polyesters III: Acyltransferase as Catalyst; 7.1 Preface
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| Abstract
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This book comprehensively covers researches on enzymatic polymerization and related enzymatic approaches to produce well-defined polymers, which is valuable and promising for conducting green polymer chemistry. It consists of twelve chapters, including the following topics: The three classes of enzymes, oxidoreductases, transferases and hydrolases, have been employed as catalysts for enzymatic polymerization and modification; Well-defined polysaccharides are produced by enzymatic polymerization catalyzed by hydrolases and transferases; Hydrolase-catalyzed polycondensation and ring-opening polymerization are disclosed to produce a variety of polyesters; Polyesters are synthesized by in-vivo acyltransferase catalysis produced by microorganisms; Enzymatic polymerization catalyzed by appropriate enzymes also produces polypeptides and other polymers; Poly(aromatic)s are obtained by enzymatic polymerization catalyzed by oxidoreductases and their model complexes; Such enzymes also induce oxidative polymerization of vinyl monomers; Enzymatic modification of polymers is achieved to produce functionalized polymeric materials; The enzymatic polymerization is a green process with non-toxic catalysts, high catalyst efficiency, green solvents and renewable starting materials, and minimal by-products; Moreover, renewable resources like biomass are potentially employed as a starting substrate, producing useful polymeric materials. This book is not only educative to young polymer chemists like graduate students but also suggestive to industrial researchers, showing the importance of the future direction of polymer synthesis for maintaining a sustainable society.
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Green chemistry.
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Polymerization.
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Green chemistry.
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Polymerization.
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| Dewey Classification
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547/.28
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| LC Classification
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QD281.P6
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| Added Entry
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Kadokawa, Jun-ichi,1964-
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Kobayashi, Shiro,1941-
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Uyama, Hiroshi
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