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" Nanoporous materials for gas storage / "
Katsumi Kaneko, Francisco Rodríguez-Reinoso, editors.
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BL
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| Record Number
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891330
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| Title & Author
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Nanoporous materials for gas storage /\ Katsumi Kaneko, Francisco Rodríguez-Reinoso, editors.
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| Publication Statement
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Singapore :: Springer,, 2019.
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| Series Statement
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Green energy and technology,
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1 online resource (x, 403 pages) :: illustrations (some color)
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| ISBN
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9789811335044
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: 9789811335051
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: 9811335044
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: 9811335052
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9789811335037
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9811335036
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| Contents
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Intro; Preface; Contents; 1 Introduction; 1.1 Introduction; 1.2 The Need for the Storage of Hydrogen, Methane, and Carbon Dioxide; 1.3 Nanoporous Materials; 1.4 Requested Properties for Nanoporous Adsorbents; References; 2 Fundamental Aspects of Supercritical Gas Adsorption; 2.1 Equation of State for Gases; 2.2 Intermolecular Interactions Between Molecules in Gas Phase; 2.3 Four Types of Molecule-Solid Interaction for Gas Storage; 2.4 Origin of Physical Adsorption; 2.5 Quasi-Vaporization of Supercritical Gas for Gas Storage; 2.5.1 Importance of Enhanced Intermolecular Interactions
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2.5.2 Simple Analysis of Quasi-vaporized Supercritical Gases2.5.3 Surface Enrichment-Induced Enhancement of Supercritical Gas Adsorption; 2.5.4 Clathrate Formation-Mediated Adsorption of Supercritical Gas; 2.6 In-Pore Phase Diagram; References; 3 Fundamental Science of Gas Storage; 3.1 Surface Excess Mass and Absolute Adsorption Amount; 3.2 Particle Density, High-Pressure Adsorption Isotherm of Supercritical Gas, and Absolute Adsorption; 3.3 Nanoporous Materials for Gas Storage; 3.4 Effect of Adsorption Enthalpy on Gas Storage; References
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4 Physical Chemistry and Engineering for Adsorptive Gas Storage in Nanoporous Solids4.1 Introduction; 4.2 Direct Experimental Measurement of Adsorptive Gas Storage; 4.3 Quantification of Adsorption on Different Substrates; 4.3.1 Adsorption on a Flat, Open Solid Surface; 4.3.2 Adsorption in Nanoporous Solids; 4.4 Experimental Measurements of Adsorption in Different Thermodynamic Frameworks; 4.4.1 Volumetric Isotherm Measurement and Data Analysis; 4.4.2 Gravimetric Isotherm Measurement and Data Analysis; 4.4.3 Conversion of Data Between Net, Excess, and Absolute Adsorption
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4.4.4 Adsorption Isotherm Data from Molecular Simulations4.5 Implications of Different Thermodynamic Frameworks on Adsorptive Gas Storage Characterization; 4.6 Challenges in Measuring High-Pressure Adsorption for Gas Storage; 4.7 Other Engineering Considerations for Adsorptive Gas Storage; 4.7.1 Residual Gas Left in Adsorptive Storage Vessel at Depletion: Isothermal Storage Capacity; 4.7.2 Impact of Heat of Adsorption on Storage Performance: Dynamic Storage Capacity; 4.7.3 Impact of Heavier Compounds on Storage Performance; References; 5 Nanoporous Carbons with Tuned Porosity
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5.1 Introduction5.2 Conventional Activation Methods; 5.2.1 Carbonization; 5.2.2 Physical Activation; 5.2.3 Chemical Activation; 5.3 Novel Approaches for Control of Microporosity; 5.3.1 Hydrothermal Carbonization; 5.3.2 Nanocasting Techniques; 5.3.2.1 Hard Templating; 5.3.2.2 Soft Templating; 5.3.3 Sol-Gel Approaches; 5.3.4 Self-Activation; 5.3.5 Carbon Molecular Sieves; 5.3.6 Carbide-Derived Carbons; 5.4 Conclusions; References; 6 Metal-Organic Frameworks; 6.1 Metal-Organic Frameworks: Construction Principles and Topology; 6.2 Historical Aspects of Discovery and Development of MOFs
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| Abstract
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This book shows the promising future and essential issues on the storage of the supercritical gases, including hydrogen, methane and carbon dioxide, by adsorption with controlling the gas-solid interaction by use of designed nanoporous materials. It explains the reason why the storage of these gases with adsorption is difficult from the fundamentals in terms of gas-solid interaction. Also, the example of industrial application of natural gas storage with adsorption is described. It consists of 16 chapters which describe fundamentals, application, key nanoporous materials (nanoporous carbon, metal organic frame works, zeolites) and their storage performance for hydrogen, methane, and carbon dioxide. Thus, this book appeals to a wide readership of the academic and industrial researchers and it can also be used in the classroom for graduate students focusing on clean energy technology, green chemistry, energy conversion and storage, chemical engineering, nanomaterials science and technology, surface and interface science, adsorption science and technology, carbon science and technology, metal organic framework science, zeolite science, nanoporous materials science, nanotechnology, environmental protection, and gas sensors.
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Gases-- Absorption and adsorption.
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Gas-solid interfaces.
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Nanostructured materials.
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Gases-- Absorption and adsorption.
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Gas-solid interfaces.
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Nanostructured materials.
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| Dewey Classification
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620.1/15
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| LC Classification
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TA418.9.N35
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| Added Entry
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Kaneko, Katsumi
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Rodríguez-Reinoso, F.,1941-
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