| Document Type
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BL
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| Record Number
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960025
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| Doc. No
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b714395
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| Main Entry
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Perchyonok, V. Tamara.
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| Title & Author
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Radical reactions in aqueous media /\ V. Tamara Perchyonok.
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| Publication Statement
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Cambridge, UK :: RSC Pub.,, ©2010.
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| Series Statement
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RSC green chemistry ;; no. 6
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| Page. NO
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xii, 129 pages :: illustrations ;; 25 cm
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| ISBN
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1849730008
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: 9781849730006
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| Bibliographies/Indexes
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Includes bibliographical references and index.
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| Contents
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Free radical chemistry and green chemistry : the historical perspective -- Basic radical chemistry : general aspects of synthesis with radicals -- Why water as a solvent? Reasons and advantages -- Reducing agents based on group 4 and aqueous media -- On the use of phosphorus hydrides as efficient hydrogen donors -- Organoboron compounds as radical reducing agents -- Carbon-carbon bond formation through radical addition chemistry -- Redox processes and electron transfer : free radicals are a central player -- Chain versus non-chain free radical processes in aqueous media -- Future directions and practical considerations.
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| Abstract
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"Recent advances in free radical chemistry in water have expanded the versatility and flexibility of homolytic bond formations in aqueous media. This textbook highlights the substantial progress which has been made in the last decade to "tame" the reactive free radical species in aqueous phase reactions." "Suitable for students of chemistry, industrial chemists and academic researchers, it combines extensive knowledge of free radical chemistry with the latest innovations and creative applications."
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"The book describes radical reactions in organic and aqueous media and their applications in total synthesis, DNA structural probing, isotope labelling, living polymerization and various other applications. It shows that, armed with an elementary knowledge of kinetics and some common sense, it is possible to harness radicals into tremendously powerful tools for solving synthetic problems.
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Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
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| Subject
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Chemical reactions.
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| Subject
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Free radical reactions.
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Free radicals (Chemistry)
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Hydrogen bonding.
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Water chemistry.
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| Subject
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Chemical reactions.
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Free radical reactions.
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Free radicals (Chemistry)
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Hydrogen bonding.
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Hydrogen bonding.
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Réactions chimiques.
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Water chemistry.
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Water chemistry.
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| Dewey Classification
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546.22
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| LC Classification
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QD169.W3P46 2009
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| Added Entry
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Royal Society of Chemistry (Great Britain)
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