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" NASICON Open Framework Structured Transition Metal Oxides for Lithium Batteries. "
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BL
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| Record Number
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968804
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| Doc. No
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b723174
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| Main Entry
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K. M. Begam
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| Title & Author
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NASICON Open Framework Structured Transition Metal Oxides for Lithium Batteries.
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| Publication Statement
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INTECH Open Access Publisher,, 2010.
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| Page. NO
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1 online resource
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| ISBN
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9533070587
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: 9789533070582
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| Abstract
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We identified a group of NASICON open framework structured polyanion materials and examined the materials for rechargeable lithium battery application. We found that the open framework structure of these materials facilitated easy insertion/extraction of lithium into/from their structure. We synthesized the materials in lithium-rich [Li2M2(MoO4)3] and lithium-free [LixM2(MoO4)3] (M= Ni, Co) phases, for the first time, by means of a low temperature soft-combustion technique. The soft-combustion synthesis usually yields single-phase materials with high phase purity and is suitable for bulk preparation of battery grade electrode powders. The materials were characterized for structure, morphology and electrochemical lithium insertion/extraction kinetics and the results were presented and discussed in the light of XRD, SEM and electrochemical techniques in relation to the electrode-active character of the materials. All the materials were found to crystallize in a single phase structure with submicron sized particles. The electrode-active behavior of the new materials was examined in a twoelectrode configuration utilizing a Li+ non-aqueous environment. Both the systems were.
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M. S. Michael
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S. R. S. Prabaharan
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